Chemoselective synthesis of first representatives of bis(diorganothiophosphinyl)selenides, (R2P=S)2Se, from secondary phosphine sulfides and elemental selenium

Author:

Artem'ev Alexander V.,Oparina Ludmila A.,Gusarova Nina K.,Kolyvanov Nikita A.,Vysotskaya Oksana V.,Bagryanskaya Irina Yu.,Trofimov Boris A.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference30 articles.

1. Palladium(II) chloride interaction with chelating bis(phosphine sulfides). Effect of the ligand structure on the complex geometry;Talanova;J. Coord. Chem.,2000

2. Reactions of bis(thiophosphoryl)disulfanes and bis(thiophosphinyl)disulfanes with metal species: an alternative, convenient route to metal complex and organometallic dithiophosphates and dithiophosphinates;Haiduc;Coord. Chem. Rev.,2002

3. Metal complexes of selenophosphinates from reactions with (R2PSe)2Se: [M(R2PSe2)n] (M=Zn(II), Cd(II), Pb(II), In(III), Ga(III), Cu(I), Bi(III), Ni(II); R=i-Pr, Ph) and [Mo2O2Se2(Se2Pi-Pr2)2];Nguyen;Chem. Commun.,2006

4. Facile and reproducible syntheses of bis(dialkylselenophosphenyl)selenides and -diselenides: X-ray structures of (i-Pr2PSe)2Se, (i-Pr2PSe)2Se2 and (Ph2PSe)2Se;Nguyen;Chem. Commun.,2006

5. For example, see: (a) W. von Gentzkow, J. Huber, H. Kapitza, W. Rogler, H.-J. Kleiner, D. Wilhelm, Epoxy resin mixtures containing phosphonic/phosphinic acid anhydride adducts, US Patent 5587243, 1996; (b) E. Wipfelder, W. Plundrich, Flame retardant reaction resin system, US Patent 5837771, 1998; (c) R. Maynard, K.I. Papathomas, M.D. Poliks, Halogen free triazines, bismaleimide/epoxy polymers, prepregs made therefrom for circuit boards and resin coated articles, and use, US Patent 6534179, 2003.

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