Orbital-scale understanding of the surface effect of the MgCl2 in the Ziegler–Natta catalyst for ethylene polymerization: A computational study

Author:

Xie KefengORCID,Huang Anping,Zhang Pingsheng,Wang Xiong,Zhang Yonghui,Ai Chunjin

Funder

National Natural Science Foundation of China

Publisher

Elsevier BV

Reference59 articles.

1. Synthesis and evaluation of a new three-metallic high-performance Ziegler-Natta catalyst for ethylene polymerization: experimental and computational studies;Abazari;Polymer Bulletin,2021

2. Spectroscopic signature and structure of the active sites in Ziegler-Natta polymerization catalysts revealed by electron paramagnetic resonance;Ashuiev;J. American Chem. Society,2021

3. Molecular and supported Ti(III)-alkyls: efficient ethylene polymerization driven by the pi-character of metal-carbon bonds and back donation from a singly occupied molecular orbital;Ashuiev;Chem. Sci.,2021

4. Polyolefin catalyst research: a product-driven industrial perspective;Atiqullah;The Chem. Rec.,2022

5. Interaction of different poisons with MgCl2/TiCl4 based Ziegler-Natta catalysts;Bahri-Laleh;Appl. Surf. Scie.,2016

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