Stoichiometric reactions of nonconjugated dienes with zirconocene derivatives. Further delineation of the scope of bicyclization and observation of novel multipositional alkene regioisomerization-Reference-Cited by-同舟云学术

Stoichiometric reactions of nonconjugated dienes with zirconocene derivatives. Further delineation of the scope of bicyclization and observation of novel multipositional alkene regioisomerization

Published:1995-04 Issue:15 Volume:51 Page:4447-4462
ISSN:0040-4020
Container-title:Tetrahedron
language:en
Short-container-title:Tetrahedron

Author:

Negishi Ei-ichi,Maye John P,Choueiry Danièle

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference46 articles.

1. Reaction of zirconocene dichloride with alkyllithiums or alkyl grignard reagents as a convenient method for generating a “zirconocene” equivalant and its use in zirconium-promoted cyclization of alkenes, alkynes, dienes, enynes, and diynes

2. Metal-promoted cyclization. 19. Novel bicyclization of enynes and diynes promoted by zirconocene derivatives and conversion of zirconabicycles into bicyclic enones via carbonylation

3. Zirconocene-promoted stereoselective bicyclization of 1,6- and 1,7-dienes to produce trans-zirconabicyclo[3.3.0]octanes and cis-zirconabicyclo[4.3.0]nonanes

4. Di(cyclopentadienyl)zirconium(II) bis(phosphine) complexes

5. Zirconocene-.eta.4-1,3-pentadiene complex and its higher homologs. A new synthetic method involving .sigma.-.pi. rearrangement of the hydrido-2,4-pentadienylzirconium species

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