The oxidative addition of a vinylic CH bond of divinyl(phenyl)phosphine at M3(CO)12 carbonyls (M Ru, Os). Stepwise formation and crystal structure of [(μ-H)Ru3(CO)8{PPh(CHCH2)2}{μ3-PPh(CHCH2) (CHCH)}]
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
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5. Chemistry of multi-site bound unsaturated ligands on metal carbonyl clusters. Intramolecular reductive coupling in the conversion of [Ru3(µ-H)(CO)9(µ3,η2-CCBut)] to the butadienyl cluster [Ru3(CO)8{µ3,η4C(But)CC(H)C(Ph)(PPh2)}], and its crystal structure. An example of ligand isomerism on metal clusters
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4. Synthesis and characterization of trinuclear osmium clusters containing diallylphosphines as hemilabile ligands: Experimental and theoretical studies of their reactivity with nucleophilic molecules;Journal of Organometallic Chemistry;2014-12
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