Mixed carbonyl–nitrile complexes of dirhenium(II). The structural characterization and reactivity of salts of the [Re2Cl3(μ-dppm)2(CO)(NCMe)n]+ cations (dppm=Ph2PCH2PPh2, n=1 or 2)-Reference-Cited by-同舟云学术

Mixed carbonyl–nitrile complexes of dirhenium(II). The structural characterization and reactivity of salts of the [Re2Cl3(μ-dppm)2(CO)(NCMe)n]+ cations (dppm=Ph2PCH2PPh2, n=1 or 2)

Published:2000-06 Issue:2 Volume:604 Page:219-228
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Chantler James,Fanwick Phillip E,Walton Richard A

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference26 articles.

1. Unusual reactivity associated with the triply bonded rhenium(Re24+) core: facile reaction of Re2Cl4(Ph2PCH2PPh2)2 with nitriles to afford the cations [Re2Cl3(Ph2PCH2PPh2)2(NCR)2]+

2. Reactions of the dirhenium(II) complexes Re2X4(dppm)2 (X = Cl or Br; dppm = Ph2PCH2PPh2) with tertiary phosphine and phosphite ligands. The isolation and characterization of the 1:1 adducts Re2X4(dppm)2(PR3) and Re2Cl4(dppm)2[P(OR)3] and the crystal structure of [Re2Cl3(dppm)2(NCEt)2]PF6

3. Further studies on the reactivity of complexes of the type cis-Re2(μ-O2CR)2X2(μ-dppm)2. The structural characterization of cis-Re2(μ-O2CCH3)2(NCBH3)2(μ-dppm)2 and [Re2Cl3(μ-dppm)2(1,2-C6H4(CN)2)2]PF6

4. Synthesis and characterization of the triply bonded (rhenium) tetrakis(cyanotrihydroborato) complex Re2(NCBH3)4(.mu.-dppm)2

5. Mixed carbonyl-isocyanide and carbonyl-nitrile complexes derived from the reactions of the multiply bonded dirhenium(II) complexes Re2X4(dppm)2(CO) (X = chloro or bromo-; dppm = Ph2PCH2PPh2). The structural characterization of Cl2Re(.mu.-Cl)(.mu.-dppm)2ReCl(CO) and Cl2Re(.mu.-Cl)(.mu.-CO)(.mu.-dppm)2ReCl(CNxylyl)

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Synthesis, spectroscopic investigation, structural characterization, and DFT calculations of [ReX2(N2COPh)(CH3PhCN)(PPh3)(2)] (X = Cl, Br);J COORD CHEM;2012

2. Rhenium Compounds;Comprehensive Organometallic Chemistry III;2007

3. The reactivity of [ReBr3(MeCN)(dppe)] towards gaseous nitric oxide. The X-ray structure of [ReBr3(MeCN)(dppe)] and [ReBr3(NO)(dppe)]0.57[ReOBr3(dppe)]0.43 and DFT calculations for [ReBr3(NO)(dppe)] and [ReOBr3(dppe)];Journal of Molecular Structure;2005-04

4. The synthesis, spectroscopic investigation, crystal and molecular structure of [ReCl3(MeCN)(dppe)] complex;Inorganic Chemistry Communications;2003-06

5. Rhenium Compounds;Multiple Bonds Between Metal Atoms