Rearrangements of ethylene oxide derivatives. V. The boron trifluoride catalysed rearrangement of some 1,1-disubstituted ethylene oxides-Reference-Cited by-同舟云学术

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Rearrangements of ethylene oxide derivatives. V. The boron trifluoride catalysed rearrangement of some 1,1-disubstituted ethylene oxides

Published:1970 Issue:10 Volume:23 Page:2077
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Blackett BN,Coxon JM,Hartshorn MP,Richards KE

Abstract

The boron trifluoride catalysed rearrangement of the unsymmetrical epoxide (3) to give aldehyde (5) proceeds by selective (c. 1.9: 1) migration of the hydrogen atom (Hb) cis to the methyl group.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

http://www.publish.csiro.au/CH/pdf/CH9702077

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