Author:
Hart N,Johns S,Lamberton J,Summons R
Abstract
Psychotridine, the major
alkaloid from Psychotria beccarioides
Wernh. has the molecular composition C55H62N10.
It has been shown to be related to hodgkinsine, and a structure (4) derived
from five Nb-methyltryptamine units is proposed. Mass spectral
evidence for the structure is supported by the conversion of psychotridine
through a pentamethiodide into a penta-indolenine base, analogous to the
tri-indolenine base derived from hodgkinsine Nb,Nb',Nb?-trimethiodide.
The structure is also supported by comparison of the 13C N.M.R.
spectra of hodgkinsine and psychotridine.
Cited by
41 articles.
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