Author:
Salah OMA,Ashby GS,Bruce MI,Pederzolli EA,Walsh JD
Abstract
Reactions between silver(1)
salts and poly(pyrazolyl)borate anions in the
presence of donor ligands have given 21 complexes of general formula AgL(RnBH4-n) [L = PPh3, P(c6H4Me)3,
P(OMe)3, P(OPh)3, AsPh3,
SbPh3, o - C6H4(
AsMe2)2 or ButNC; RnBH4-n
= HB(pz)3, HB(Me2pz)3 orB(pz)4], and [Ag(HBR3)]2(dppe)
(R = PZ or Me2pz) and {[Ag(HBR3)](dppm)}n (R =
PZ, n = 1 ; R = Me2pz, n = 2). Their possible structures are
discussed in the light of various spectroscopicdata obtained for them.
Cited by
22 articles.
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