Metal Exchange within a Body-Centred Cubic Hydrogen-Bonded Network-Reference-Cited by-同舟云学术

Metal Exchange within a Body-Centred Cubic Hydrogen-Bonded Network

Published:2007 Issue:1 Volume:60 Page:68
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Abrahams Brendan F.,FitzGerald Nicholas J.,Hudson Timothy A.,Robson Richard,Shalders Richard D.

Abstract

A hydrogen bonded network of composition Zn8(C4O7)4(H2O)12·hydrate was shown to undergo a single crystal to single crystal exchange process when crystals are immersed in a concentrated aqueous solution of Ni(ii). In the exchange process, half of the zinc(ii) centres are replaced by nickel(ii) centres. The process of metal ion exchange was monitored using IR spectroscopy. Crystal structures of the transformed crystal and the product generated from a direct synthetic approach are presented.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

http://www.publish.csiro.au/CH/pdf/CH06334

Reference26 articles.

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3. A 3D metal-organic network, [Cu2(glutarate)2(4,4′-bipyridine)], that exhibits single-crystal to single-crystal dehydration and rehydrationElectronic supplementary information (ESI) available: experimental details, IR, TGA and XRPD of all compounds. See http://www.rsc.org/suppdata/cc/b3/b301219k/.

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