Abstract
The formulae and properties
of certain blue and violet peroxyohromium compounds have been
investigated, and structures suggested. The blue adducts can be represented as
organic base, Cr(O2)2O, blue anions as Cr(O2)2OX-
where X is Cl or Br, and the violet anions as Cr(O2)2O2H-,
where His thought to be hydrogen-bonded between two oxygen atoms. A
relationship between these different forms is suggested. The various properties
investigated for the peroxychromium compounds include magnetic
susceptibilities, number of peroxy groups, conductivities, molecular weight
measurements, and visible, infrared, and N.M.R. spectra.
Cited by
10 articles.
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