Abstract
Dye sensitized photooxidation of 1,3-diphenyl-2-pyrazoline in methylene
chloride yields 1,3-diphenyl- pyrazole and in
methanol yields 1,3-diphenylpyrazole and β,β-dimethoxypropiophenone.
The formation of 1,3-diphenylpyrazole is quenched by the singlet oxygen
quencher β-carotene, whereas the formation of β-dimethoxypropiophenone
does not appear to be affected. The photooxidation in
methanol shows a large deuterium isotope effect, the rate being approximately
ten times faster in methanol[D4] than in methanol. Under anaerobic
conditions, 1,3-diphenyl-2-pyrazoline quenches the phosphorescence of eosin Y
and rose bengal B with quenching rate constants 1.0 x
108 and 3.0 x 108 1, mol-1 s-1,
respectively. Photobleaching of the dyes is shown to
occur by reduction to the semi-reduced dye radicals.
Cited by
33 articles.
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