Author:
Bruce MI,Williams ML,Patrick JM,White AH
Abstract
The X-ray structure of the
CH2Cl2-solvate of OsCl(PPh3)2(η-C5H5)
has been determined, and compared with that of the non-solvated ruthenium
analogue. Crystal are triclinic, space group P1, with a 14.490(3), b 14.110(3),
c 9.937(3) �, α 99.84(2), β
106.57(2), γ 100.08(2)� and Z 2. Refinement of 5297 data with I > 3σ(I)
converged with R 0.033, R' 0.038. The Os-C and Os-Cl distances are c.0.007 �
longer than corresponding Ru-C and Ru-Cl distances, while the Os-P separations are 0.017 � shorter than the Ru-P
separations.
Cited by
21 articles.
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