Chemistry of the Podocarpaceae. LXIII. Ring-C oxidation of totarol

Author:

Cambie RC,Hayward RC,Palmer BD

Abstract

Methods for the conversion of totarol (1) into the catechol derivative (2) are described. Oxidative cleavage of the derived methyl ether (13) by ozonolysis affords a high-yielding route to a compound (34) with potential as a nagilactone precursor.

Publisher

CSIRO Publishing

Subject

General Chemistry

Cited by 18 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Some Synthetic Uses of Halides;PATAI'S Chemistry of Functional Groups;2009-12-15

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3. Utilization of a copper-catalyzed diaryl ether synthesis for the preparation of verbenachalcone;Tetrahedron;2002-09

4. N-Bromosuccinimide-Dimethylformamide;Encyclopedia of Reagents for Organic Synthesis;2001-04-15

5. The synthesis and antibacterial activity of totarol derivatives. part 2: modifications at C-12 and O-13;Bioorganic & Medicinal Chemistry;2000-07

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