Author:
Brown RD,Pez GP,O'Dwyer MF
Abstract
An investigation of the infrared spectrum
of gaseous thio-thionyl fluoride (SSF2) results in the following
assignment of fundamentals: A': v1 760.5�0.2cm-1, v2
718.5�0.2 cm-1, v3 411.2�0.4cm-1, v4
364.1�0.3 cm-1. A": v5 692.3�0.8cm-1,
v6 337.6�0.4 cm-1. A normal coordinate
vibrational analysis has been performed and a set of ten force constants
evaluated. Some conclusions are given regarding the electronic structure of SSF2.
Thermodynamic functions based on the usual assumptions have been calculated for
SSF2. A set of potential constants has been evaluated for disulphur monoxide, SSO, using the available infrared data.
Cited by
19 articles.
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