Author:
Engelhardt LM,Newman PWG,Raston CL,White AH
Abstract
The crystal structure of
the title compound, [Ni(NH20H)6] SO4, has been
determined at 298 K by photographic methods; the structure was solved by the
heavy atom method and refined by block diagonal least-squares procedures to a
residual of 0.095 (1166 independent reflections). Crystal data: triclinic, PI, a
14.026(3), b 6.741(2), c 6.358(1) �, α-98.35(2), β
79.57(1), γ 95.06(2)�, Z 2. In the two
crystallographically independent centrosymmetric cations, the nickel atoms are octahedrally coordinated by the ligand nitrogen atoms,
(Ni-N), 2.12 �, <N-O), 1.44 �. The Ni-N-O angles range from 110 to 117�. The
sulphate geometry is normal and undistorted.
Cited by
13 articles.
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