Author:
Clezy PS,Fookes CJR,Smythe GA
Abstract
The preparation of a meso-thioacetoxyporphyrin by ring
synthesis from a dipyrrylthione is described together with the reaction of
thiocyanogen with octaethylporphyrin and coproporphyrin 11 to give meso-thiocyanatoporphyrins. Attempts to
produce meso-mercaptoporphyrins by
hydrolysis of either meso-thioacetoxy-
or meso-thiocyanato-porphyrins
failed. Instead the corresponding disulfides were produced and the properties
of this latter group are described.
Cited by
4 articles.
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