Regiocontrolled Opening of 2-Methyltetrahydrofuran with Various Boron Reagents-Reference-Cited by-同舟云学术

Regiocontrolled Opening of 2-Methyltetrahydrofuran with Various Boron Reagents

Published:2006 Issue:9 Volume:59 Page:657
ISSN:0004-9425
Container-title:Australian Journal of Chemistry
language:en
Short-container-title:Aust. J. Chem.

Author:

Roy Chandra D.

Abstract

Regiocontrolled halogenative cleavage of 2-methyltetrahydrofuran with various B-bromoboranes, by a predominantly SN2-type mechanism favouring the formation of primary bromide, is described. A comparative study of the relative reactivities of BH2Br·SMe2, BHBr2·SMe2, BBr3, (MeO)2BBr, and MeOBBr2 revealed that the newly synthesized (MeO)2BBr is a highly promising regioselective reagent, especially at lower temperatures.

Publisher

CSIRO Publishing

Subject

General Chemistry

Link

http://www.publish.csiro.au/CH/pdf/CH06272

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