Abstract
A Monte Carlo simulation
study of the force between two adsorbing walls is described. The adsorbate is in equilibrium with either a bulk gas or a
liquid phase. The force is correlated with the adsorption, singlet and radial
distribution functions, all of which vary with the distance of separation of
the walls, when this is of the order of a few atomic diameters. When the bulk
phase is a gas, a new type of surface transition occurs in which the distance
of wall separation is one of the determining degrees of freedom.
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