Author:
Arthur NL,Christie JR,Mitchell GD
Abstract
The hydrogen abstraction
reactions of SiH2Cl2 and SiHCl2 with CF3
radicals
CF3+SiH2Cl2 → CF3H + SiHCl2
CF3+SiH2Cl3 → CF3H +
SiHCl3
have been studied in the
temperature ranges 65-227�and 64-294�, respectively. The rate constants, based
on the value of 1013.36 cm3 mol-1 s-1 for the
recombination of CF3 radicals, are given by (k in cm3 mol-1 s-1, E in J mol-1):
logk1 = (12.08 �
0.04)-(25600 � 280)/19.145T
logk2 = (11.92 �
0.02)-(27020 � 160)/19.145T
Cited by
6 articles.
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