Author:
Bruce Michael I.,Skelton Brian W.,Smith Mark E.,White Allan H.
Abstract
Iodination of FcC ≡ CH with morpholinium iodide gave structurally
characterized iodoethynylferrocene, FcC ≡ CI; its reaction with
Co2(CO)8 affords
{Co2(CO)6}2(µ:µ-FcC2C2Fc),
also characterized by an X-ray structure determination. This compound is
formed by deiodinative coupling of the iodoalkyne and subsequent addition of a
Co2(CO)6 group to each C ≡ C
triple bond in the resulting diyne.
Cited by
23 articles.
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