Affiliation:
1. Department of Chemistry, School of Chemical Sciences, University of Illinois, Urbana, Illinois 61801
Abstract
Polarization scrambling by high pressure cell windows as a function of pressure up to 2 kbar has been measured for two window materials and two sizes of plug apertures. Measured scrambling was about 1% for quartz, 0.5% for float glass, and decreased with decreasing aperture size. The amount of scrambling decreased significantly with time when the cell was left pressurized. A qualitative explanation of the results, based on changes in the P44 Pockets coefficient with pressure is given.
Subject
Spectroscopy,Instrumentation
Cited by
28 articles.
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