A New Method for Separating Configurational and Constitutional Chiralities Using Diffuse Reflectance Circular Dichroism (DRCD)-Reference-Cited by-同舟云学术

A New Method for Separating Configurational and Constitutional Chiralities Using Diffuse Reflectance Circular Dichroism (DRCD)

Published:2013-10 Issue:10 Volume:67 Page:1210-1213
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Harada Takunori¹,Nakano Taku²,Moriyama Hiroshi²,Tajima Nobuo³,Yokota Haruo¹,Kawakami Ryo¹,Mishima Kenji¹

Affiliation:

1. Fukuoka University, Department of Chemical Engineering, Faculty of Engineering, 8-19-1, Nanakuma, Jonan-ku, Fukuoka 814-0180, Japan

2. Toho University, Department of Chemistry, Faculty of Science, 2-2-1, Miyama, Funabashi, Chiba 274-8510, Japan

3. National Institute for Materials Science (NIMS), First-Principles Simulation Group, Computational Materials Science Center, 1-2-1, Sengen, Tsukuba, Ibaraki 305-0047, Japan

Abstract

Solid-state chiral chemistry has attracted significant scientific interest because of its application in the chiral-selective production, chiral recognition, resolution, and detection of enantiomers of a chiral compound. Combining a novel diffuse reflectance circular dichroism (DRCD) technique with powder X-ray crystallographic analysis, we investigated the origin of chiral properties from the molecular and supramolecular chiralities and the possibility of separating independent CD signals from the superimposed CD signal resulting from different chiral origins.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/13-07087

Reference37 articles.

1. A solid-state dedicated circular dichroism spectrophotometer: Development and application

2. The Application of Polarization Modulation Method to Investigate the Optical Homogeneity of Polymer Films

3. Circular Dichroism Measurement of a Protein in Dried Thin Films

4. Phase-Sensitive Supramolecular Chirogenesis in Bisporphyrin Systems

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Plasticizer‐Induced Enhancement of Mesoscale Dissymmetry in Thin Films of Chiral Polymers with Variable Chain Length;Advanced Materials;2023-12-04

2. Transmission vs. Diffuse Transmission in Circular Dichroism: What to Choose for Probing Solid-State Samples?;Chirality;2015-06-03