Raman Apparatus Using Laser Excitation and Polarization Measurements. Rotational Spectrum of Fluorine-Reference-Cited by-同舟云学术

Raman Apparatus Using Laser Excitation and Polarization Measurements. Rotational Spectrum of Fluorine

Published:1969-01 Issue:1 Volume:23 Page:8-12
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Claassen Howard H.¹,Selig Henry¹,Shamir Jacob¹

Affiliation:

1. Department of Inorganic and Analytical Chemistry, The Hebrew University of Jerusalem, Jerusalem, Israel

Abstract

Various schemes are compared for measuring depolarization factors in Raman spectra with laser excitation. Optical systems are discussed for producing a laser beam free of unwanted emission lines and for focusing scattered light on the slit and on the detector. The rotational spectrum of gaseous F2 has been used to determine a rotational constant of Bo=0.8841 ±0.0006 cm−1, corresponding to r0=1.4168±0.0005 Å.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/000370269774381265

Reference6 articles.

1. High-Resolution Raman Spectroscopy of Gases with cw-Laser Excitation*

2. The vibrational frequency of the oxygen molecule (O2+) cation

3. THE RAMAN SPECTRUM OF FLUORINE

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