Factor Analysis and Fourier Transform Infrared Spectra of Compatible Blends of Polyphenylene Oxides and Polystyrene

Author:

Koenig J. L.1,Rodriquez M. J. M. Tovar1

Affiliation:

1. Department of Macromolecular Science, Case Western Reserve University, Cleveland, Ohio 44106

Abstract

Fourier transform infrared spectra has been obtained of compatible blends of polyphenylene oxide (PPO) and polystyrene (PS). An incompatible blend of polyphenylene oxide and poly(4-chlorostyrene) (P4C1S) was also studied. Factor analysis was used to determine the number of components in the blend system. The data indicated that three components existed in the PPO/PS compatible system and only two in the PPO/P4C1S system. The interaction spectrum in the compatible blend was determined by a double-subtraction technique and used to analyze the blend system for the magnitude of the interaction as a function of composition. The interaction was maximum at a 70/30 composition in agreement with other data.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

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1. Spectroscopic analysis of compatibilized polymer blends;Compatibilization of Polymer Blends;2020

2. Identification and Measurement of Intermolecular Interaction in Polyester/Polystyrene Blends by FTIR-Photoacoustic Spectrometry;Journal of Polymers and the Environment;2015-07-03

3. Thermodynamics of Polymer Blends;Polymer Blends Handbook;2014

4. Poly(phenylene oxide);Handbook of Engineering and Speciality Thermoplastics;2011-06-08

5. Synthesis and characterization of poly(phenylene oxide) graft copolymers by atom transfer radical polymerizations;European Polymer Journal;2009-08

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