Synthesis and characterization of copper(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone)-Reference-Cited by-同舟云学术

Synthesis and characterization of copper(II) complex with 2,6-diacetylpyridine-bis(phenylhydrazone)

Published:2021 Issue:1 Volume:11 Page:24-28
ISSN:2738-0971
Container-title:Bulletin of Natural Sciences Research
language:en
Short-container-title:Bull Nat Sci Research

Author:

Belošević Svetlana,Radanović Mirjana,Rodić Marko^ORCID,Leovac Vukadin

Abstract

The syntheses, physicochemical and structural properties of the novel Cu(II) complex with 2,6-diacetylpyridine bis(phenylhydrazone) (L), of the formula [CuL 2 ]Br 2 are presented. In the reaction of warm MeOH solutions of the ligand, 2,6-diacetylpyridine bis(phenylhydrazone) and CuBr 2 in molar ratio 2:1 resulted in formation of black single crystals of the bis(ligand) complex. This is the first Cu(II) complex with this ligand that is characterized by SC-XRD. Two ligand molecules are coordinated in the usual tridentate mode, via nitrogen atoms of the pyridine ring, and two azomethine nitrogen atoms, forming distorted octahedral environments of the metal ion.

Funder

Ministry of Education, Science and Technological Development of the Republic of Serbia

Publisher

Centre for Evaluation in Education and Science (CEON/CEES)

Subject

General Earth and Planetary Sciences,General Environmental Science

Link

https://scindeks-clanci.ceon.rs/data/pdf/2738-0971/2021/2738-09712101024B.pdf

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1. Reactions of copper(II) bromide with 2,6-diacetylpyridine bis(phenyl-hydrazone) (L)-molecular and crystal structure of L and its mixed-valence complex [cuiil2][cui2br4];Journal of the Serbian Chemical Society;2021