Isolation of a Benzene Valence Isomer with One-Electron Phosphorus-Phosphorus Bonds-Reference-Cited by-同舟云学术

Isolation of a Benzene Valence Isomer with One-Electron Phosphorus-Phosphorus Bonds

Published:1998-03-27 Issue:5359 Volume:279 Page:2080-2082
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Canac Yves¹²,Bourissou Didier¹²,Baceiredo Antoine¹²,Gornitzka Heinz¹²,Schoeller Wolfgang W.¹²,Bertrand Guy¹²

Affiliation:

1. Y. Canac, D. Bourissou, A. Baceiredo, H. Gornitzka, G. Bertrand, Laboratoire de Chimie de Coordination du CNRS, 205, route de Narbonne, 31077 Toulouse Cedex, France.

2. W. W. Schoeller, Fakultät für Chemie der Universität, Postfach 10 01 31, D-33615 Bielefeld, Germany.

Abstract

A tetraphosphabenzene analog of the postulated anti -tricyclohexylene, a singlet biradical valence isomer of benzene, has been isolated. The tricyclic derivative features one-electron phosphorus-phosphorus bonds, which result from the π*-π* interaction between two diphosphirenyl radicals. Such one-electron bonds may play a wider role in phosphorus chemistry.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference65 articles.

1. Gutman I., Potgieter J. H., J. Chem. Educ. 71, 222 (1994);

2. Shakespeare W. C., Johnson R. P., J. Am. Chem. Soc. 112, 8578 (1990);

3. Christl M., Braun M., Müller G., Angew. Chem. Int. Ed. Engl. 31, 473 (1992).

4. Bock H., Angew. Chem. Int. Ed. Engl. 28, 1627 (1989).

5. van Tamelen E. E., Pappas S. P., J. Am. Chem. Soc. 85, 3297 (1963);

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