Toroidal polar topology in strained ferroelectric polymer

Author:

Guo Mengfan1ORCID,Guo Changqing2ORCID,Han Jian1ORCID,Chen Shulin3,He Shan1ORCID,Tang Tongxiang1ORCID,Li Qian14ORCID,Strzalka Joseph4ORCID,Ma Jing1ORCID,Yi Di1ORCID,Wang Ke1ORCID,Xu Ben1,Gao Peng3ORCID,Huang Houbing5ORCID,Chen Long-Qing6ORCID,Zhang Shujun7ORCID,Lin Yuan-Hua1ORCID,Nan Ce-Wen1ORCID,Shen Yang18ORCID

Affiliation:

1. State Key Lab of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China.

2. School of Aerospace Engineering, Beijing Institute of Technology, Beijing 100081, China.

3. Electron Microscopy Laboratory and International Center for Quantum Materials, School of Physics, Peking University, Beijing 100871, China.

4. X-ray Science Division, Argonne National Laboratory, Lemont, IL 60439, USA.

5. Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China.

6. Department of Materials Science and Engineering, The Pennsylvania State University, University Park, State College, PA 16802, USA.

7. Institute for Superconducting and Electronic Materials, Australian Institute for Innovative Materials, University of Wollongong, Wollongong, New South Wales 2500, Australia.

8. Center for Flexible Electronics Technology, Tsinghua University, Beijing 100084, China.

Abstract

Polarization hits a bull's-eye Polymer-based ferroelectric materials are attractive because they can be solution processed cheaply and have much greater flexibility than ceramics. Guo et al. found concentric circular bands of polarization in a ferroelectric polymer that look like a bull's-eye target (see the Perspective by Martin). This self-organized toroidal texture is aligned perpendicularly to the axis of the polymer chains, allowing the authors to demonstrate selective absorption of infrared radiation and manipulation of terahertz radiation. This distinct structure in a polymer could be of interest for exploring and using other exotic effects. Science , this issue p. 1050 ; see also p. 992

Funder

National Outstanding Youth Science Fund Project of National Natural Science Foundation of China

Innovative Research Group Project of the National Natural Science Foundation of China

National Key Research and Development Program of China Stem Cell and Translational Research

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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