Comment on "Efficient Photochemical Water Splitting by a Chemically Modified n-TiO 2 " (II)

Author:

Hägglund Carl1,Grätzel Michael2,Kasemo Bengt3

Affiliation:

1. Department of Applied Physics Chalmers University of Technology Göteborg, Sweden

2. Laboratory of Photonics and Interfaces Swiss Federal Institute of Technology Lausanne, Switzerland

3. Department of Applied Physics Chalmers University of Technology

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference7 articles.

1. Efficient Photochemical Water Splitting by a Chemically Modified n-TiO 2

2. R. F. Service, Science297, 2189 (2002).

3. Spectral solar irradiance data sets for selected terrestrial conditions

4. Stability and Photoresponse of Nanocrystalline n ‐ TiO2 and n ‐ TiO2 / Mn2 O 3 Thin Film Electrodes during Water Splitting Reactions

5. In both cases ( 1 4 ) a natural gas flame kept at 850°C was employed to oxidize a Ti metal sheet in oxygen atmosphere during 13 min resulting in a mainly rutile phase n-TiO 2 layer. The samples were characterized using a 5 M KOH electrolyte a Pt counter electrode and a standard calomel reference electrode with illumination from a 150-W xenon arc lamp at 50 mW/cm 2 irradiance in ( 4 ) and 40 mW/cm 2 irradiance in ( 1 ). It is notable that the material stability was found to be poor in ( 4 ) in contrast to the claims in ( 1 ).

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