Terminal coordination of diatomic boron monofluoride to iron-Reference-Cited by-同舟云学术

Terminal coordination of diatomic boron monofluoride to iron

Published:2019-03-15 Issue:6432 Volume:363 Page:1203-1205
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Drance Myles J.¹^ORCID,Sears Jeffrey D.²^ORCID,Mrse Anthony M.¹^ORCID,Moore Curtis E.¹^ORCID,Rheingold Arnold L.¹,Neidig Michael L.²^ORCID,Figueroa Joshua S.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, Mail Code 0358, La Jolla, CA 92093-0358, USA.

2. Department of Chemistry, University of Rochester, Rochester, NY 14627, USA.

Abstract

Iron's new Best Friend Carbon monoxide (CO) is one of the most widely studied ligands in the chemistry of transition metals. One of its distinguishing features is a two-way bonding motif, in which CO donates electrons to the metal while the metal simultaneously engages in “back bonding” in the other direction. Theory has suggested that the isoelectronic boron fluoride diatomic, BF, would be even more effective at both types of bonding. However, it has been challenging to prepare the requisite compounds for comparison. Drance et al. now report synthesis of a terminal iron-BF complex, with donor and acceptor characteristics that compare favorably to analogous CO and N 2 complexes. Science , this issue p. 1203

Funder

National Science Foundation

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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