Hierarchical Porous Polymer Scaffolds from Block Copolymers

Author:

Sai Hiroaki1,Tan Kwan Wee1,Hur Kahyun1,Asenath-Smith Emily1,Hovden Robert23,Jiang Yi4,Riccio Mark5,Muller David A.23,Elser Veit4,Estroff Lara A.1,Gruner Sol M.346,Wiesner Ulrich1

Affiliation:

1. Department of Materials Science and Engineering, Cornell University, Ithaca, NY 14853, USA.

2. School of Applied and Engineering Physics, Cornell University, Ithaca, NY 14853, USA.

3. Kavli Institute at Cornell for Nanoscale Science, Ithaca, NY 14853, USA.

4. Department of Physics, Cornell University, Ithaca, NY 14853, USA.

5. Cornell University Institute of Biotechnology, Cornell University, Ithaca, NY 14853, USA.

6. Cornell High Energy Synchrotron Source (CHESS), Cornell University, Ithaca, NY 14853, USA.

Abstract

A Complicated Scaffold, Simply Materials with tailored pore structures can be useful as catalysis supports and for lightweight materials. When preparing medical scaffolds, restrictive preparation conditions have to be met, which can prohibit multistep preparation procedures. Sai et al. (p. 530 ) describe a method for making porous polymers containing both relatively large (several microns) interconnecting pores and a second population of ∼ tens of nanometer pores. The process exploits spinodal decomposition of a block copolymer blended with small-molecule additives and requires a simple washing step with water, methanol, or ethanol.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference31 articles.

1. B.-L. Su C. Sanchez X.-Y. Yang Hierarchically Structured Porous Materials from Nanoscience to Catalysis Separation Optics Energy and Life Science (Wiley-VCH Weinheim Germany 2012).

2. I. W. Hamley The Physics of Block Copolymers (Oxford Univ. Press Oxford 1998).

3. Polymerization of monomers containing functional silyl groups. 5. Synthesis of new porous membranes with functional groups

4. Bicontinuous Cubic Block Copolymer Photonic Crystals

5. Ordered Nanoporous Polymers from Polystyrene−Polylactide Block Copolymers

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