Metal-organic magnets with large coercivity and ordering temperatures up to 242°C

Author:

Perlepe Panagiota12ORCID,Oyarzabal Itziar13ORCID,Mailman Aaron4ORCID,Yquel Morgane12,Platunov Mikhail5ORCID,Dovgaliuk Iurii6ORCID,Rouzières Mathieu1ORCID,Négrier Philippe7ORCID,Mondieig Denise7ORCID,Suturina Elizaveta A.8ORCID,Dourges Marie-Anne9ORCID,Bonhommeau Sébastien9ORCID,Musgrave Rebecca A.1ORCID,Pedersen Kasper S.110ORCID,Chernyshov Dmitry6ORCID,Wilhelm Fabrice5ORCID,Rogalev Andrei5,Mathonière Corine2ORCID,Clérac Rodolphe1ORCID

Affiliation:

1. Université de Bordeaux, CNRS, Centre de Recherche Paul Pascal, UMR 5031, F-33600 Pessac, France.

2. Université de Bordeaux, CNRS, Bordeaux INP, ICMCB, UMR 5026, F-33600 Pessac, France.

3. Chemistry Faculty, University of the Basque Country, UPV/EHU, 20018 Donostia-San Sebastián, Spain.

4. Department of Chemistry, University of Jyväskylä, FI-40014 Jyväskylä, Finland.

5. ESRF-The European Synchrotron, CS 40220, F-38043 Grenoble Cedex 9, France.

6. Swiss-Norwegian Beamlines at the European Synchrotron Radiation Facility, F-38000 Grenoble, France.

7. Université de Bordeaux, CNRS, Laboratoire Ondes et Matière d’Aquitaine, UMR 5798, F-33400 Talence, France.

8. Department of Chemistry, University of Bath, Claverton Down, Bath BA2 7AY, UK.

9. Université de Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, F-33400 Talence, France.

10. Department of Chemistry, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark.

Abstract

Lightening the load Permanent magnets are generally produced from solid metals or alloys. Less dense compositions involving lighter elements tend to demagnetize well below room temperature or under modest applied external fields. Perlepe et al. now report that chemical reduction of a low-density chromium-pyrazine network produces a magnet that remains stable above 200°C and resists demagnetization with 7500-oersted coercivity at room temperature. The straightforward synthetic route to the material shows promise for broad exploration of potential applications. Science , this issue p. 587

Funder

Villum Fonden

Eusko Jaurlaritza

Centre National de la Recherche Scientifique

Conseil Régional Aquitaine

Academy of Finland

University of Bordeaux

Quantum Matter Bordeaux

University of Jyväskylä

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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