Highly stretchable polymer semiconductor films through the nanoconfinement effect

Author:

Xu Jie1,Wang Sihong1,Wang Ging-Ji Nathan1,Zhu Chenxin2,Luo Shaochuan3,Jin Lihua45,Gu Xiaodan16,Chen Shucheng1,Feig Vivian R.7,To John W. F.1,Rondeau-Gagné Simon1,Park Joonsuk7,Schroeder Bob C.1,Lu Chien1,Oh Jin Young1,Wang Yanming7,Kim Yun-Hi8,Yan He9,Sinclair Robert7,Zhou Dongshan3,Xue Gi3,Murmann Boris2,Linder Christian5,Cai Wei4,Tok Jeffery B.-H.1,Chung Jong Won110,Bao Zhenan1

Affiliation:

1. Department of Chemical Engineering, Stanford University, Stanford, CA 94305, USA.

2. Department of Electrical Engineering, Stanford University, Stanford, CA 94305, USA.

3. Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.

4. Department of Mechanical Engineering, Stanford University, Stanford, CA 94305, USA.

5. Department of Civil and Environmental Engineering, Stanford University, Stanford, CA 94305, USA.

6. Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, Menlo Park, CA 94025, USA.

7. Department of Materials Science and Engineering, Stanford University, Stanford, CA 94305, USA.

8. Department of Chemistry and RINS, Gyeongsang National University, Jinju 660-701, South Korea.

9. Department of Chemistry and Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration & Reconstruction, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong.

10. Samsung Advanced Institute of Technology Yeongtong-gu, Suwon-si, Gyeonggi-do 443-803, South Korea.

Abstract

Trapping polymers to improve flexibility Polymer molecules at a free surface or trapped in thin layers or tubes will show different properties from those of the bulk. Confinement can prevent crystallization and oddly can sometimes give the chains more scope for motion. Xu et al. found that a conducting polymer confined inside an elastomer—a highly stretchable, rubber-like polymer—retained its conductive properties even when subjected to large deformations (see the Perspective by Napolitano). Science , this issue p. 59 ; see also p. 24

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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