Large-Pore Apertures in a Series of Metal-Organic Frameworks-Reference-Cited by-同舟云学术

Large-Pore Apertures in a Series of Metal-Organic Frameworks

Published:2012-05-25 Issue:6084 Volume:336 Page:1018-1023
ISSN:0036-8075
Container-title:Science
language:en
Short-container-title:Science

Author:

Deng Hexiang¹,Grunder Sergio²,Cordova Kyle E.¹,Valente Cory²,Furukawa Hiroyasu¹,Hmadeh Mohamad¹,Gándara Felipe¹,Whalley Adam C.²,Liu Zheng³,Asahina Shunsuke⁴,Kazumori Hiroyoshi⁴,O’Keeffe Michael¹,Terasaki Osamu⁵⁶⁷,Stoddart J. Fraser²⁷,Yaghi Omar M.¹⁷

Affiliation:

1. Center for Reticular Chemistry, Center for Global Mentoring, University of California, Los Angeles (UCLA)–U.S. Department of Energy (DOE) Institute for Genomics and Proteomics, and the Department of Chemistry and Biochemistry, UCLA, Los Angeles, CA 90095, USA.

2. Center for the Chemistry of Integrated Systems, Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.

3. Nanotube Research Center, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba 305-0046, Japan.

4. SMBU, JEOL, Akishima, Tokyo 196-8558, Japan.

5. Department of Materials and Environmental Chemistry, Stockholm University, Stockholm 10691, Sweden.

6. EXSELENT, Stockholm University, Stockholm 10691, Sweden.

7. NanoCentury KAIST Institute and Graduate School of Energy, Environment, Water, and Sustainability (World Class University), Daejeon 305-701, Republic of Korea.

Abstract

Maximizing Molecular Pore Diameters Amorphous materials, such as activated carbon, can have pore diameters of several nanometers, but the synthesis of ordered structures with very large pore diameters is often thwarted by the creation of interpenetrating networks or difficulties in removing guest molecules. Deng et al. (p. 1018 ) avoided these problems in the synthesis of metal-organic frameworks (MOFs) with very large diameters (some exceeding 3 nanometers) by using a combination of short and very long linking groups. The compounds formed channels almost 10 nanometers in diameter that could be visualized by electron microscopy and that were large enough to accommodate protein molecules.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference37 articles.

1. Crystal Structure and Guest Uptake of a Mesoporous Metal–Organic Framework Containing Cages of 3.9 and 4.7 nm in Diameter

2. A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis

3. Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage

4. High Capacity Hydrogen Adsorption in Cu(II) Tetracarboxylate Framework Materials: The Role of Pore Size, Ligand Functionalization, and Exposed Metal Sites

5. Rod Packings and Metal−Organic Frameworks Constructed from Rod-Shaped Secondary Building Units

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