Clathrate colloidal crystals

Author:

Lin Haixin12ORCID,Lee Sangmin3ORCID,Sun Lin24ORCID,Spellings Matthew3ORCID,Engel Michael5ORCID,Glotzer Sharon C.367ORCID,Mirkin Chad A.124ORCID

Affiliation:

1. Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.

2. International Institute for Nanotechnology, Northwestern University, Evanston, IL 60208, USA.

3. Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109, USA.

4. Department of Materials Science and Engineering, Northwestern University, Evanston, IL 60208, USA.

5. Institute for Multiscale Simulation, Friedrich-Alexander University Erlangen-Nürnberg, 91058 Erlangen, Germany.

6. Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109, USA.

7. Biointerfaces Institute, University of Michigan, Ann Arbor, MI 48109, USA.

Abstract

Turning colloidal gold into clathrates Clathrates contain extended pore structures that can trap other molecules. Lin et al. created colloidal analogs of clathrates in which bipyramidal gold nanoparticles functionalized with DNA molecules assembled into polyhedral clusters to create open-pore structures (see the Perspective by Samanta and Klajn). These clathrate colloidal crystals exhibit extraordinary structural complexity and substantially broaden both the scope and the possibilities provided by DNA-inspired methodologies. Science , this issue p. 931 ; see also p. 912

Funder

National Science Foundation

U.S. Department of Energy

Air Force Office of Scientific Research

China Scholarship Council

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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