Imaging the onset of the resonance regime in low-energy NO-He collisions

Abstract

Ultracold molecular collision dynamics Ultracold collision dynamics are of great importance in understanding the quantum nature of chemical interactions, but achieving the ultracold regime for molecules is challenging. Traditional techniques based on alternative routes to assemble the ultracold atomic constituents are only able to produce a type of ultracold molecules that cannot probe state-selective dynamics. Using Stark deceleration and velocity map–imaging techniques, de Jongh et al. achieved the ultracold regime directly for a nitric oxide–helium system and measured the state-to-state cross sections for inelastic scattering with high precision (see the Perspective by Yang and Yang). The observed scattering resonances confirmed high sensitivity to the underlying interaction potential because only the most accurate electronic structure theory could reproduce their structure. Science , this issue p. 626 ; see also p. 582