Affiliation:
1. Institut für Chemie, Freie Universität Berlin, Fabeckstrasse 34-36, D-14195 Berlin, Germany.
Abstract
The first metal-xenon compound with direct gold-xenon bonds is achieved by reduction of AuF
3
with elemental xenon. The square planar AuXe
4
2+
cation is established by a single-crystal structure determination, with a gold-xenon bond length of approximately 274 picometers. The bonding between gold and xenon is of the σ donor type, resulting in a charge of approximately 0.4 per xenon atom.
Publisher
American Association for the Advancement of Science (AAAS)
Cited by
307 articles.
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