Chameleon-like elastomers with molecularly encoded strain-adaptive stiffening and coloration

Author:

Vatankhah-Varnosfaderani Mohammad1ORCID,Keith Andrew N.1ORCID,Cong Yidan1ORCID,Liang Heyi2ORCID,Rosenthal Martin3ORCID,Sztucki Michael3,Clair Charles4,Magonov Sergei5,Ivanov Dimitri A.67ORCID,Dobrynin Andrey V.2ORCID,Sheiko Sergei S.1ORCID

Affiliation:

1. Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599, USA.

2. Department of Polymer Science, University of Akron, Akron, OH, 44325-3909, USA.

3. European Synchrotron Radiation Facility, F-38043 Grenoble, France.

4. Université de Haute Alsace, Laboratoire de Physique et Mécanique Textiles, F-68093 Mulhouse Cedex, France.

5. Scanning Probe Microscopy (SPM) Labs, Tempe, AZ 85283, USA.

6. Institut de Sciences des Matériaux de Mulhouse-IS2M, CNRS UMR 7361, F-68057 Mulhouse, France.

7. Lomonosov Moscow State University, Faculty of Fundamental Physical and Chemical Engineering, Leninskie Gory 1/51, 119991 Moscow, Russian Federation.

Abstract

Active camouflage from a polymer Human skin is soft and compliant, but it can quickly become stiff when deformed to prevent injury. Chameleon skin can change color when the animal goes from a relaxed to an excited state. Although these properties can be captured individually in synthetic materials, the combination of different dynamic responses can be hard to control. Vatankhah-Varnosfaderani et al. created triblock copolymers of the ABA variety, where the A blocks have a linear structure and the B blocks are like bottlebrushes. When strained, these polymers stiffened like human skin and changed color, thus giving the materials a range of adaptive properties. Science , this issue p. 1509

Funder

National Science Foundation

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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