The Impact of Aerosols on Solar Ultraviolet Radiation and Photochemical Smog

Author:

Dickerson R. R.12,Kondragunta S.12,Stenchikov G.12,Civerolo K. L.12,Doddridge B. G.12,Holben B. N.12

Affiliation:

1. R. R. Dickerson, S. Kondragunta, G. Stenchikov, K. L. Civerolo, B. G. Doddridge, Department of Meteorology, University of Maryland, College Park, MD 20742, USA.

2. B. N. Holben, NASA Goddard Space Flight Center, Greenbelt, MD 20742, USA.

Abstract

Photochemical smog, or ground-level ozone, has been the most recalcitrant of air pollution problems, but reductions in emissions of sulfur and hydrocarbons may yield unanticipated benefits in air quality. While sulfate and some organic aerosol particles scatter solar radiation back into space and can cool Earth's surface, they also change the actinic flux of ultraviolet (UV) radiation. Observations and numerical models show that UV-scattering particles in the boundary layer accelerate photochemical reactions and smog production, but UV-absorbing aerosols such as mineral dust and soot inhibit smog production. Results could have major implications for the control of air pollution.

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

Reference55 articles.

1. Photochemical production of tropospheric ozone has been studied extensively [

2. Urban Air Pollution: State of the Science

3. ; National Academy of Sciences Rethinking the Ozone Problem in Urban and Regional Air Pollution (National Academy of Sciences Washington DC 1991); U.S. Environmental Protection Agency National Air Quality and Emissions Trends Report 1995 (EPA454/R-96-005 1996);

4. Tropospheric Air Pollution: Ozone, Airborne Toxics, Polycyclic Aromatic Hydrocarbons, and Particles

5. . The effect of aerosols on UV flux and photochemical ozone production near Earth's surface has generally been assumed to be small and negative that is the presence of aerosols reduces slightly the rate of smog formation [L. Zafonte P. Rieger J. Holmes Environ. Sci. Technol. 11 483 (1977);

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