Chiromagnetic nanoparticles and gels

Abstract

Boosting chiral nanoparticle responses Optical nanomaterials that combine chirality and magnetism are useful for magneto-optics and as chiral catalysts. Although chiral inorganic nanostructures can exhibit high circular dichroism, modulating this optical activity has usually required irreversible chemical changes. Yeom et al. synthesized paramagnetic cobalt oxide (Co 3 O 4 ) nanoparticles with l - and d -cysteine surface ligands. These ligands created chiral distortions of the crystal lattices, and this anisotropy led to much stronger chiroptical activity. The circular dichroism in the ultraviolet of nanoparticle gels could be modulated with magnetic fields of ∼1.5 tesla. Science , this issue p. 309