Liquid Phase Morphology Control of ZnO Nanowires, Ellipse Particles, Hexagonal Rods, and Particle in Aqueous Solutions

Abstract

Liquid phase morphology control of ZnO crystals was realized with simple aqueous solution system. ZnO nanowires were successfully fabricated at 50∘C. They were over 50 μm in length and about 100 nm in width. Aspect ratio was estimated to be over 500. They had no branches and were obtained without aggregations. Curved nano-wires clearly indicated high flexibility and high mechanical strength. Additionally, ellipse particles, hexagonal rods and particles were fabricated in the solutions. Morphology, crystal growth speed, and preferred growth faces were well-controlled by precise adjustment of growth conditions.