Spatial distribution, risk assessment and sources of heavy metals in roadside soils exposed to the Zhengzhou-Kaifeng intercity railway in Huanghuai Plain, China

Abstract

Abstract Heavy metal accumulation in soil can seriously harm human health, and it is necessary to identify the accumulation status and access the potential risks for local pollution control and sustainable economic development. This study evaluated the pollution level, spatial distribution, potential risk and sources of soil heavy metals including As, Co, Cr, Cu, Zn, Pb, Ni, and Cd along the Zhengzhou-Kaifeng intercity railway and compared pollution characteristics in north side soils with south side soils of the railway. A total of 260 soil samples were collected from a section along the railway, and the average concentrations of As, Co, Cr, Cu, Zn, Pb, Ni, and Cd were 5.54, 10.58, 63.38, 24.40, 97.85, 60.63, 26.01, and 0.36 mg∙kg−1, respectively. In practice, only the average Zn and Pb contents in soils were slightly higher than their corresponding risk screening values. The heavy metal enrichment in the north side soils was marginally lower than that in the south side soils. The spatial distribution of soil heavy metals except Pb could be mainly influenced by the different land use types. The geoaccumulation index and potential ecological risk of a single heavy metal indicated that Cd was the major contaminant with moderate pollution and high ecological risks in the south side soils and none to moderate pollution and moderate ecological risks in the north side soils. However, the mean multimetal potential ecological risk values suggested that the north side soils were at low ecological risks and the south side soils were at moderate ecological risks. The comprehensive non-carcinogenic risks and total carcinogenic risks for adults were low and acceptable, respectively. Combined Pearson correlation analysis, PCA, and APCS-MLR analyses identified that the contributions of natural sources, mixed sources of industrial and traffic activities, agricultural activities, and other sources were 57.49%, 21.44%, 12.67% and 8.40%, respectively, and the major soil pollution Cd was mainly related to mixed sources of industrial and traffic activities. Therefore, continuous soil heavy metal monitoring is essential to elucidate the long-term railway operation effect on soil heavy metal accumulation.