Abstract
Abstract
The interactions between phenylglycine and some transition metal ions (UO22+,La3+ and Zr4+) were studied at three ionic strengths [(µ = 0.05, 0.10 and 0.15) M KNO3] and three temperatures [(25, 35 and 45) ºC] in aqueous media by using Bjerrum’s potentiometric technique. The stoichiometric and thermodynamic stability constants as well as the degree of complexation for all studied systems (\(\stackrel{-}{\text{n}}\)) were determined and discussed. The standard thermodynamic parameters (Δ pKº and Δlog Kº) and the thermodynamic parameter differences (ΔGº, ΔΔGº, ΔHº, ΔΔHº, ΔSº, and ΔΔSº) were calculated for all possible reactions. Advanced discussions of these functions as well as the factors that may control the complexation processes from the thermodynamic point of view have been reported.
Publisher
Research Square Platform LLC
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