Affiliation:
1. Zhejiang Sci-Tech University
2. Huzhou Horizontal Na Energy Technology Co., Ltd
Abstract
Abstract
The development of advanced electrode materials for sodium-ion batteries (SIBs) is crucial for the progression of energy storage technologies. In this study, we successfully fabricated V5S8/CoS nanoparticles confined within self-supported carbon nanofibers (CNFs) using a facile electrospinning method followed by a sulfidation process. Extensive characterization of the resulting V5S8/CoS-CNFs revealed their unique structural attributes, featuring a one-dimensional nanofiber morphology with enhanced Na+ transport pathways. These V5S8/CoS-CNFs exhibited a remarkable reversible capacity of 201 mAh g−1 even at a high current density of 5 A g−1, along with a stable cycling performance of 165 mA h g−1 after 300 cycles at 2 A g−1. The incorporation of both V5S8 and CoS within the nanofiber structure substantially enhanced the pseudocapacitance effect, thereby improving sodium storage capabilities. The exceptional electrochemical properties of the binder-free V5S8/CoS-CNFs anode can be attributed to its heterogeneous composition embedded within CNFs. This composition effectively boosts the rate of sodium ion diffusion by generating a built-in electric field (BEF) at the V5S8 and CoS interface, alleviating volume stress during charge-discharge processes and enhancing overall conductivity. Our findings underscore the potential of V5S8/CoS-CNFs as high-performance anode materials for SIBs, offering valuable insights into the design and development of advanced electrode materials for future energy storage applications.
Publisher
Research Square Platform LLC