H5PV2Mo10O40 as an efficient catalyst for the oxidation of thiols to the corresponding disulfides using hydrogen peroxide as the oxidant-Reference-Cited by-同舟云学术

H5PV2Mo10O40 as an efficient catalyst for the oxidation of thiols to the corresponding disulfides using hydrogen peroxide as the oxidant

Published:2011 Issue:7 Volume:76 Page:955-963
ISSN:0352-5139
Container-title:Journal of the Serbian Chemical Society
language:en
Short-container-title:JSCS

Author:

Shojaei Abdollah¹,Rezvani Mohamad¹,Heravi Majid²

Affiliation:

1. University of Guilan, Faculty of Science, Department of Chemistry, Rasht, Iran

2. Alzzahra University, School of Science, Department of Chemistry, Vanak, Tehran, Iran

Abstract

The H5PV2Mo10O40 catalyzed the oxidation of thiols to their homodisulfides using hydrogen peroxide as the oxidant under mild conditions is reported. This system provides an efficient, convenient and practical method for the syntheses of symmetrical disulfides. In this work, comparisons of Keggin and Dawson type polyoxometalates are addressed in term of relative stability, hardness and acidity.

Publisher

National Library of Serbia

Subject

General Chemistry

Reference13 articles.

1. Applications of Sulfoxides to Asymmetric Synthesis of Biologically Active Compounds

2. Building bridges: disulphide bond formation in the cell

3. Selenium, carbon monoxide and water as a new reduction system: Reductive cleavage of disulfides and diselenides to thiols and selenols

4. Sodium Chlorite - Yet Another Oxidant for Thiols to Disulphides

5. Catalytic oxidation of thiols to disulfides using iodine and CeCl3·7H2O in graphite

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