Photocatalytic degradation of thiotriazinone, stable hydrolysis product of antibiotic ceftriaxone

Abstract

In this work, the efficiency of direct photolytic and photocatalytic degradation of thiotriazinone, stable hydrolysis product of antibiotic ceftriaxone, was examined. The efficiency of photocatalytic degradation of 0.05 mmol/dm3 thiotriazinone solution was investigated using commercially available TiO2 Hombikat catalyst under simulated solar irradiation, as well as in the absence/presence of ammonium persulfate ((NH4)2S2O8) as electron acceptor. It was found that the optimal conditions for photocatalytic degradation of thiotriazinone were: catalyst loading 1.0 mg/cm3 of TiO2 Hombikat, electron acceptor 3 mmol/dm3 of (NH4)2S2O8 solution, and pH 7.6. Under the stated conditions 76.0% of thiotriazinone was degradated after 60 min of irradiation. The kinetics of degradation was followed by UFLC-DAD technique.