Influence of the particle size reduction on magnetic properties of electron-doped Ca1-xYxMnO3

Author:

Alqat Aboalqasim1,Gebrel Zohra1,Spasojevic Vojislav1ORCID,Kusigerski Vladan1ORCID,Boskovic Snezana1ORCID,Blanusa Jovan1ORCID

Affiliation:

1. Vinča Institute of Nuclear Sciences, Condensed Matter Physics Laboratory, Belgrade

Abstract

The electron-doped magnetic nanoparticles of Ca1-xYxMnO3 (x = 0, 0.05, 0.10, 0.15, 0.20, and 0.30) manganite with an average particle size of 50 nm are analyzed and discussed in relation to their bulk counterparts. Nanoparticle samples show dominant anti-ferromagnetic ordering with a significant increase of coercivity, with the maximum value of 0.9 T for x = 0. Particle size reduction in Ca1-xYxMnO3 retains the bulk-like magnetic behavior of samples having up to 15% of Y3+, with the small ferromagnetic contribution from disordered surface spins. Suppression of charge ordering state and enhancement of saturation magnetization were found in samples with higher Y3+ concentration (x = 0.2, 0.3), indicating high ferro-magnetic contribution in these samples.

Funder

Ministry of Education, Science and Technological Development of the Republic of Serbia

Publisher

National Library of Serbia

Subject

Safety, Risk, Reliability and Quality,Nuclear Energy and Engineering

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