Affiliation:
1. Faculty of Science, Novi Sad, Serbia and Montenegro
Abstract
Three new bis(ligand) iron(III) complexes were prepared with the deprotonated ONX ligands (X = O,S,N), pyridoxal semi-, thiosemi- and S-methylisothiosemicarbazones (H2L1, H2L2 and H2L3, respectively) of the formulas [Fe(HL1,2)L1,2].4H2O and [Fe(HL3)2]OAc.2H2O. The compounds were characterized by elemental analysis, conductometric and magnetochemical measurements, as well as by IR and UV-vis spectra. Detailed voltammetric investigations were carried out in DMF solutions in the presence of several supporting electrolytes to study the nature of the electrochemical processes and solution equilibria.
Publisher
National Library of Serbia
Cited by
10 articles.
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