Synthesis and characterization of zinc(II), palladium(II) and platinum(II) complexes with 2’-[1-(2-pyridinyl)- ethylidene]oxamohydrazide: The crystal structure of biss2'-[1-(2-pyridinyl)ethylidene]oxa-Reference-Cited by-同舟云学术

Synthesis and characterization of zinc(II), palladium(II) and platinum(II) complexes with 2’-[1-(2-pyridinyl)- ethylidene]oxamohydrazide: The crystal structure of biss2'-[1-(2-pyridinyl)ethylidene]oxa

Published:2004 Issue:8-9 Volume:69 Page:651-660
ISSN:0352-5139
Container-title:Journal of the Serbian Chemical Society
language:en
Short-container-title:JSCS

Author:

Andjelkovic Katarina¹,Jakovljevic Gordana¹,Zlatovic Mario¹^ORCID,Tesic Zivoslav¹^ORCID,Sladic Dusan¹,Howing Jonas²,Tellgren Roland²

Affiliation:

1. Faculty of Chemistry, Belgrade, Serbia and Montenegro

2. Department of Materials Chemistry, The Ångström Laboratory, Uppsala, Sweden

Abstract

Complexes of Zn(II), Pd(II) and Pt(II) with 2?-[1-(2-pyridinyl)ethylidene ]oxamohydrazide (Hapsox) were synthesized and their structures were determined. All the complexes are of a neutral type with two apsox ligands coordinated to Zn(II) and one apsox ligand coordinated to Pd(II) or Pt(II). In each case, the polydentate was coordinated via pyridine and hydrazone nitrogens and ?-oxyazine oxygen, forming an octahedral geometry around Zn(II), and a square planar one around Pd(II) and Pt(II). The structure determination was performed by IR, 1H-NMR and 13C-NMR spectroscopy, and for the Zn(II) complex by X-ray structure analysis.

Publisher

National Library of Serbia

Subject

General Chemistry

Reference8 articles.

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2. The Fe(III) complexes with a doubly deprotonated polydentate acylhydrazone: crystal structure of the first diamagnetic μ-oxo-diiron(III) complex

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4. Synthesis and Structural Characterization of the Co(III) Complex with 2'-[1-(2-Pyridinyl)-Ethylidene]-Oxamohydrazide (Hapsox): The Crystal Structure of Bis-{2'-[1-(2-Pyridinyl)-Ethylidene]-Oxamohydrazido} Cobalt(III) Perchlorate, [Co(apsox)2]ClO4

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