Solid state interactions in the systems CaO(CaCO3)-Fe2O3 and CuFe2O4-CaO

Author:

Boyanov B.S.1

Affiliation:

1. University of Plovdiv, Faculty of Chemistry, Plovdiv, Bulgaria

Abstract

The solid state interactions in the systems CaO(CaCO3)-Fe2O3 and CuFe2O4-CaO have been studied using X-ray diffraction analysis. The influence of the temperature on the ferrite formation process has been investigated in the range of 900-1200 oC and duration up to 360 min. It has been shown that a mixture of ferrites forms at 1000 oC and interaction of 240 min. The exchange reactions in the systems CuFe2O4-CaO and Cu0.5Zn0.5Fe2O4-CaO have been studied, too. It has been established that Ca2+ ions exchange Cu2+ and Zn2 partially and the solubility of copper and zinc in a 7 % sulfuric acid solution increases 10-15 times.

Publisher

National Library of Serbia

Subject

Materials Chemistry,Metals and Alloys,Mechanics of Materials,Geotechnical Engineering and Engineering Geology

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