NATÜREL ZEYTİNYAĞI TAĞŞİŞİNİN TESPİTİNDE STEROL KOMPOZİSYONU, ECN42 FARKI VE FTIR SPEKTROSKOPİSİNİN KULLANIMININ KARŞILAŞTIRMALI OLARAK İNCELENMESİ

Author:

KARACAN Ebru1ORCID,ÖZDİKİCİERLER Onur1ORCID,YEMİŞÇİOĞLU Fahri1ORCID

Affiliation:

1. EGE UNIVERSITY, FACULTY OF ENGINEERING, DEPARTMENT OF FOOD ENGINEERING

Abstract

Due to its high price and consumer demand, virgin olive oil is an essential product vulnerable to deception for unfair economic gain. In our research, sunflower, palm olein and cottonseed oil were used as adulterants in different amounts for the preparation of adulterated samples. Sterol composition, the difference in theoretical and actual equivalent carbon number 42 triglycerides (ΔECN42) value and FTIR spectra were used to classify the adulterated and virgin olive oil samples. Decision trees on Δ7-stigmastenol and campesterol allowed the detection of 10% and higher adulteration. ΔECN42 ad FTIR provided good detection of the adulterated samples, even for the mixed oils at 1% concentration. However, the detecting performance of the FTIR decreased as the virgin olive oil sample set expanded with different seasons and varieties. Correct multivariate approach and FTIR data selection significantly influence the performance of FTIR spectroscopy for detecting VOO adulteration.

Funder

Ege Üniversitesi Bilimsel Araştırma Projeleri Koordinatörlüğü ve TÜBİTAK

Publisher

Association of Food Technology, Turkey

Subject

General Medicine

Reference37 articles.

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2. Anonymous (2017). Standard for olive oils and olive pomace. Codex Alimentarius Council. http://www.fao.org/fao-who-codexalimentarius/committees/committee-detail/es/?committee=CCFO. (Accessed 09 February 2023).

3. Anonymous (2017b). Determination of fatty acid methyl esters by gas chromatography. International Olive Council. International Olive Council Standard Method.

4. Anonymous (2017c). Determination of the difference between actual and theoretical content of triacyglycerols with ECN42. International Olive Council. International Olive Council Standard Method.

5. Anonymous (2022). Commission Delegated Regulation (EU) 2022/2104 of 29 July 2022 supplementing Regulation (EU) No 1308/2013 of the European Parliament and of the Council as regards marketing standards for olive oil, and repealing Commission Regulation (EEC) No 2568/91 and 2022/2104. European Commission. Official Journal of the European Union.

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